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Maleic Acid

CAS Number: 110-16-7

Maleic Acid, also known as cis-butenedioic acid, is a colorless crystalline organic dicarboxylic acid used primarily as a chemical intermediate and precursor in industrial manufacturing. Its chemical formula is C₄H₄O₄ and its CAS number is 110-16-7. Maleic acid is widely used in the production of fumaric acid, unsaturated polyester resins, and surface coatings, and serves as an adhesion promoter, corrosion inhibitor, and anti-scaling agent across a broad range of industrial applications.

Maleic Acid is typically supplied as a white crystalline solid and is available in bulk quantities, as well as bags, drums, and custom packaging options depending on application requirements.

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Description

Maleic Acid (C₄H₄O₄) is a colorless, crystalline solid with a faint acidulous odor and a characteristic astringent taste. It is a cis-isomer of butenedioic acid, distinguishing it from its trans-isomer counterpart, fumaric acid. Maleic acid is a dicarboxylic acid, meaning it contains two carboxyl groups, with the molecular structure HO₂CCH=CHCO₂H.

Maleic acid is primarily produced by the hydration of maleic anhydride, which is itself derived from the catalytic oxidation of benzene or butane. It is highly soluble in water and soluble in acetone and dioxane, but sparingly soluble in benzene and toluene.

Maleic acid is combustible, though difficult to ignite, and is considered toxic, causing extreme irritation to the eyes, skin, and respiratory system. Appropriate personal protective equipment should be used when handling the material.

In industrial applications, maleic acid serves as a key precursor to fumaric acid through catalytic isomerization. It is used as an adhesion promoter for substrates including nylon and zinc-coated metals, and functions as a corrosion inhibitor and anti-scaling agent in water treatment and industrial systems. It also serves as a reactive intermediate in the synthesis of resins, coatings, plasticizers, and agricultural chemicals.

Maleic acid is used in the textile industry for dyeing and finishing naturally occurring fibers, and finds application in the production of malic acid through hydration.

Applications / Use Cases

Maleic Acid is used across several industries and applications, including:

  • Precursor to fumaric acid via catalytic isomerization
  • Production of unsaturated polyester resins and alkyd resins
  • Adhesion promoter for nylon, zinc-coated metals, and other substrates
  • Corrosion inhibitor and anti-scaling agent in water treatment systems
  • Chemical intermediate in the synthesis of plasticizers and lubricant additives
  • Dyeing and finishing of naturally occurring textile fibers
  • Agricultural chemical intermediate including herbicide and pesticide production
  • Production of malic acid through hydration
  • Copolymer production for surface coatings, adhesives, and specialty polymers

Industries Served

  • Chemical Manufacturing & Intermediates
  • Resins & Coatings
  • Water Treatment
  • Textiles
  • Agriculture & Agrochemicals
  • Plastics & Plasticizers
  • Laboratory & Research

Chemical Properties

Property Value
Chemical Name Maleic Acid
CAS Number 110-16-7
Molecular Formula C₄H₄O₄
Appearance White crystalline solid
Odor Faint acidulous odor
Solubility Highly soluble in water; soluble in acetone and dioxane
Melting Point 130–131°C
Boiling Point 135°C (decomposes)
Density 1.59 g/cm³
Stability Combustible; irritant to eyes, skin, and respiratory system

Packaging & Availability

Maleic Acid is available in a range of packaging formats to meet your operational needs:

  • Bags
  • Drums
  • Bulk quantities

Custom packaging and supply solutions are available based on your application and volume requirements.

Synonyms / Alternate Names

  • cis-Butenedioic Acid
  • cis-1,2-Ethylenedicarboxylic Acid
  • Maleinic Acid
  • Toxilic Acid
  • 2-Butenedioic Acid (Z)

Why Buy From The Chemical Company

  • Reliable sourcing and consistent product quality
  • Flexible packaging and distribution options
  • Industry expertise across chemical manufacturing, resins, and industrial markets
  • Responsive customer support and technical guidance

Maleic Acid FAQs

What is Maleic Acid used for?

Maleic Acid is primarily used as a chemical intermediate in the production of fumaric acid, unsaturated polyester resins, plasticizers, and agricultural chemicals. It is also used as an adhesion promoter, corrosion inhibitor, anti-scaling agent, and in the dyeing and finishing of textile fibers.

What is the difference between Maleic Acid and Fumaric Acid?

Maleic Acid and Fumaric Acid are geometric isomers of butenedioic acid. Maleic Acid is the cis-isomer, meaning both carboxyl groups are on the same side of the double bond, while Fumaric Acid is the trans-isomer. Fumaric acid is more stable and less soluble in water. Maleic acid is commonly converted to fumaric acid through catalytic isomerization.

What is the CAS number for Maleic Acid?

The CAS number for Maleic Acid is 110-16-7.

Is Maleic Acid hazardous?

Yes. Maleic Acid is considered toxic and causes extreme irritation to the eyes, skin, and respiratory system. It is combustible, though difficult to ignite. Appropriate personal protective equipment including gloves, goggles, and respiratory protection should be worn when handling the material.

How is Maleic Acid produced?

Maleic Acid is produced commercially by the hydration of maleic anhydride, which is itself derived from the catalytic oxidation of benzene or butane. It can also be produced as a byproduct in the manufacture of phthalic anhydride.

How is Maleic Acid supplied?

Maleic Acid is available in bags, drums, and bulk quantities depending on your volume and application requirements. Contact The Chemical Company for current packaging options, lead times, and supply chain updates.

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