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Sodium Citrate

CAS Number: 68-04-2

Sodium Citrate, also known as trisodium citrate, is the trisodium salt of citric acid with the molecular formula C₆H₅Na₃O₇ and CAS number 68-04-2. It presents as a white, crystalline powder with a saline, mildly tart flavor. Sodium citrate is one of the most widely used food additives in the world, employed as a buffering agent, emulsifying salt, flavoring agent, and preservative across food and beverage, pharmaceutical, personal care, cleaning, and industrial applications.

Sodium Citrate is available in 25kg, 1,000kg, and 1,100kg bags.

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Description

Sodium Citrate (C₆H₅Na₃O₇) is a white, odorless crystalline powder that is highly soluble in water. It is mildly basic and is most commonly encountered in its dihydrate form. Trisodium citrate is the most prevalent of the three sodium salts of citric acid, though the term sodium citrate is commonly used to refer to all three. It is produced commercially by neutralizing citric acid with sodium hydroxide or sodium carbonate.

Sodium citrate functions primarily as a buffering agent, used in combination with citric acid to provide precise pH control across a wide range of food, beverage, pharmaceutical, and cosmetic formulations. It is also a powerful chelating agent, capable of binding trace metal ions to prevent oxidation and spoilage.

In the food industry, sodium citrate is widely used as an emulsifying salt in processed cheese products, allowing cheese to melt smoothly without becoming greasy. It is used as a flavoring agent in carbonated beverages, drink mixes, gelatin, ice cream, jams, sweets, milk powder, and wine. In the pharmaceutical industry, the citrate ion chelates calcium ions, reducing the tendency for blood to clot, making sodium citrate a key ingredient in blood anticoagulant formulations. It is also used in effervescent tablets, pH buffering systems, and as a counterion in pharmaceutical salts.

In cleaning and detergent applications, sodium citrate serves as a sequestering builder that reduces water hardness, enhances surfactant performance, and assists in the removal of calcium and rust deposits. In industrial applications, it is used in electroplating baths, textile finishing, construction as a set retardant for gypsum plasters, and in oil recovery and flue gas desulfurization processes.

Applications / Use Cases

Sodium Citrate is used across several industries and applications, including:

  • Emulsifying salt in processed and sliced cheese products
  • Buffering agent in combination with citric acid for pH control in food and beverages
  • Flavoring and preservative agent in carbonated soft drinks, juice drinks, and drink mixes
  • Ingredient in gelatin, ice cream, jams, sweets, milk powder, and ready meals
  • Blood anticoagulant in pharmaceutical and medical applications
  • Effervescent tablet and preparation formulations
  • pH buffering in pharmaceutical, cosmetic, and personal care products
  • Antioxidant and chelating agent in food and pharmaceutical formulations
  • Sequestering builder in laundry care, dish washing, and industrial cleaning products
  • Electroplating bath buffering and complexing agent
  • Set retardant for gypsum plasters in construction
  • Textile finishing and leather processing
  • Oil drilling and flue gas desulfurization

Industries Served

  • Food & Beverage
  • Pharmaceuticals & Healthcare
  • Personal Care & Cosmetics
  • Cleaning & Detergents
  • Industrial Manufacturing
  • Construction
  • Textiles & Leather
  • Oil & Gas

Chemical Properties

Property Value
Chemical Name Sodium Citrate (Trisodium Citrate)
CAS Number 68-04-2
Molecular Formula C₆H₅Na₃O₇
Appearance White crystalline powder
Odor Odorless
Solubility Highly soluble in water
Melting Point 300°C (decomposes)
pH (5% solution) 7.5–9.0
Taste Saline, mildly tart
Stability Stable under normal storage conditions

Packaging & Availability

Sodium Citrate is available in a range of packaging formats to meet your operational needs:

  • 25kg Bags
  • 1,000kg Bags
  • 1,100kg Bags

Custom packaging and supply solutions are available based on your application and volume requirements. Contact The Chemical Company for current lead times and supply chain updates.

Synonyms / Alternate Names

  • Trisodium Citrate
  • Trisodium 2-Hydroxypropane-1,2,3-tricarboxylate
  • Citric Acid Trisodium Salt
  • Sodium Citrate Anhydrous
  • Sodium Citrate Dihydrate
  • E331 (food additive designation)

Why Buy From The Chemical Company

  • Reliable sourcing and consistent product quality
  • Flexible packaging and distribution options
  • Industry expertise across food, pharma, personal care, and industrial markets
  • Responsive customer support and technical guidance

Sodium Citrate FAQs

What is Sodium Citrate used for?

Sodium Citrate is most commonly used as a buffering agent, emulsifying salt, flavoring agent, and preservative in food and beverage products. Key applications include processed cheese, carbonated beverages, drink mixes, and ice cream. It is also widely used in pharmaceuticals as a blood anticoagulant and pH buffer, and in cleaning products as a sequestering builder.

What is the difference between Sodium Citrate and Citric Acid?

Citric Acid is a weak organic acid with a sharp, sour taste. Sodium Citrate is the sodium salt of citric acid and is mildly basic with a saline, lightly tart flavor. When used together, they form an effective buffering system capable of maintaining precise pH control across a wide range of food, beverage, pharmaceutical, and cosmetic applications.

What is the CAS number for Sodium Citrate?

The CAS number for Sodium Citrate (trisodium citrate) is 68-04-2.

Is Sodium Citrate food grade?

Yes. Sodium Citrate is widely recognized as safe for use in food and beverages and is designated E331 as a food additive. It is used globally across food-grade, pharmaceutical-grade, and industrial-grade applications.

Why is Sodium Citrate used in processed cheese?

Sodium Citrate acts as an emulsifying salt in processed cheese, allowing the cheese to melt smoothly and evenly without separating into greasy and watery components. It stabilizes the protein structure of the cheese during heating, producing a uniform, creamy texture.

How is Sodium Citrate supplied?

Sodium Citrate is available in 25kg bags, 1,000kg bags, and 1,100kg bags. Contact The Chemical Company at (401) 360-2800 for current pricing, lead times, and supply chain updates.

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