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Calcium Chloride

Calcium Chloride is an ionic compound of calcium and chlorine with the chemical formula CaCl2 and CAS 10043-52-4. At room temperature, it is a colorless crystalline solid that is highly soluble in water. Calcium chloride is used in industry as a de-icer, in road surfacing to suppress the formation of dust, in water treatment to increase the hardness of water in swimming pools, and as an additive in plastics and fire extinguishers.

Shipping / Request a Quote

Calcium Chloride is available for shipping throughout the continental United States with a one-to-two week lead time, subject to availability. It is supplied as a dry white powder or flake packed in 25 kg bags; liquid solution and special packaging may be available on request. Contact The Chemical Company for current pricing, packaging options, lead times, and supply chain updates.

Description

The Chemical Company’s Calcium Chloride (CaCl₂) is an ionic compound of calcium and chlorine that appears as a white to off-white crystalline solid, flake, or powder. It is odorless, highly hygroscopic, and deliquescent — meaning it will absorb enough atmospheric moisture to eventually dissolve into a concentrated brine solution. In the United States, most calcium chloride is obtained by purification of naturally occurring brine deposits, while significant quantities are also produced as a byproduct of the Solvay process and from the reaction of limestone with hydrochloric acid.

One of the most widely applied inorganic salts in the world, Calcium Chloride is valued for six key properties: hygroscopicity, exothermic dissolution, freezing point depression, high solubility, high solution density, and reactivity as a calcium and chloride ion source. These properties drive its use across de-icing, desiccation, food processing, oil and gas drilling, concrete acceleration, water treatment, and refrigeration. TCC supplies calcium chloride in anhydrous, dihydrate, and liquid solution forms across technical and food-grade specifications.

Calcium Chloride outperforms sodium chloride as a de-icing agent on two fronts: its dissolution is exothermic — actively generating heat that melts ice on contact — and it depresses the freezing point of water to -52°C (-62°F) at eutectic concentration, versus only -21°C (-6°F) for rock salt. It carries E-number E509 and is GRAS-listed by the FDA, with food-grade uses spanning vegetable firming, tofu coagulation, cheesemaking, and brewing water adjustment.

The ionic compound is highly toxic, harmful if swallowed, causes serious eye damage, and exposure may cause respiratory irritation. It is not combustible but gives off irritating or toxic fumes or gases in a fire. Because of its hygroscopic nature, the hazardous compound must be kept in tightly-sealed containers.

Physical Properties

Property Value
Molecular Formula CaCl₂
Molecular Weight 110.98 g/mol (anhydrous)
Appearance White crystalline solid, powder, flake, or granule
Odor Odorless
Density (anhydrous) 2.15 g/cm³
Density (dihydrate) 1.85 g/cm³
Melting Point (anhydrous) 772°C (1422°F)
Boiling Point (anhydrous) 1,935°C (3,515°F)
Solubility in Water 74.5 g/100 mL at 20°C; 159 g/100 mL at 100°C (anhydrous)
Heat of Dissolution -82.8 kJ/mol (exothermic; solution heats significantly on dissolution)
Eutectic Point 29.8 wt% CaCl₂; freezing point -51.7°C (-61°F)
Freezing Point Depression Effective to -52°C vs. -21°C for NaCl
Hygroscopicity Absorbs moisture above 42% relative humidity; deliquescent
Available Hydrate Forms Anhydrous (CaCl₂), Monohydrate, Dihydrate (most common), Tetrahydrate, Hexahydrate
Liquid Solution Density 8.32–11.97 lbs/gal depending on concentration
pH (aqueous solution) Slightly alkaline to neutral (~6.5–8.5)
Incompatibilities Soluble carbonates, phosphates, sulfates, tartrates; bromine trifluoride; zinc (moisture)
Food Additive Status E509; GRAS (FDA); included in FDA Inactive Ingredients Database
Available Grades Technical, Food Grade (FCC), USP/NF, Anhydrous, Dihydrate, Liquid Solution (29–40%)

Applications / Use Cases

  • De-icing and anti-icing of roads, highways, parking lots, and airport runways
  • Dust suppression and road stabilization on unpaved surfaces
  • Concrete set accelerator (1–2% addition accelerates early strength development)
  • Direct kiln additive in Portland Cement manufacture
  • Gypsum aridizing agent to reduce water demand and increase product density
  • Desiccant for drying gases and organic liquids in industrial and laboratory settings
  • Dehumidification and desiccant cooling systems
  • Oil well drilling mud densifier and shale stabilizer
  • Completion and packer fluid in well workover operations
  • Cement additive for oil well cementing to accelerate set time
  • Swimming pool water hardness adjustment (calcium hardness increaser)
  • Wastewater treatment — precipitation of fluorides, phosphates, and heavy metals
  • Oil/water separation aid in oily wastewater streams
  • Food firming agent for canned vegetables, tomatoes, and pickles (E509)
  • Coagulant in tofu and soy product manufacture
  • Cheesemaking — curd formation aid in pasteurized milk
  • Brewing water mineral adjustment and sodium alkalinity removal
  • Caviar substitute production from fruit and vegetable juices
  • Low-temperature brine for refrigeration plants and cooling systems
  • Agricultural implement tire ballast for improved traction in cold climates
  • Additive in plastics and fire extinguisher formulations
  • Drainage aid in wastewater treatment systems
  • Fabric softener and textile processing applications
  • Activated charcoal production
  • Ceramic slipware — clay particle suspension agent
  • Flux in Davy process for sodium metal production via electrolysis
  • Biochemical reagent — increases cell membrane permeability for genetic transformation
  • IV pharmaceutical calcium supplementation (USP grade)

Synonyms / Alternate Names

  • Calcium chloride
  • CaCl₂
  • Calcium dichloride
  • Calcium chloride anhydrous
  • Calcium chloride dihydrate (CaCl₂·2H₂O)
  • Muriate of lime
  • Fixed sal ammoniac (historical)
  • E509 (food additive designation)

CAS Number: 10043-52-4 (anhydrous); 10035-04-8 (dihydrate)

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